Search results for "Cathode catalyst"

showing 3 items of 3 documents

Linear, tripodal, macrocyclic: Ligand geometry and ORR activity of supported Pd(II) complexes

2021

Abstract The novel ligand H3L designed to spontaneously adsorb onto MWCNT via electron-deficient pyrimidine residues and bind metal cations is used to prepare an oxygen reduction reaction (ORR) cathode catalyst based on supported Pd(II) complexes. Herein we report the synthesis of the ligand, its solution behaviour (protonation constants, binding constants for the test cation Cu(II), UV evidence of Cu(II) and Pd(II) complexes formation) and ORR performances together with XPS and STEM characterization. Tripodal nature of the H3L ligand frame it in-between previously studied macrocyclic and linear open chain ligands, allowing to draw meaningful comparisons.

Pyrimidine010405 organic chemistryLigandProtonation010402 general chemistry01 natural sciences0104 chemical sciencesCathode catalystInorganic ChemistryMetalchemistry.chemical_compoundAdsorptionX-ray photoelectron spectroscopychemistryvisual_artPolymer chemistryMaterials Chemistryvisual_art.visual_art_mediumMacrocyclic ligandPhysical and Theoretical ChemistryInorganica Chimica Acta
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Cu-B alloy - analysis of use possibility as fuel cell cathode catalyst

2016

In recent years there has been a development of non-conventional and renewable sources of energy. One such sources of energy are fuel cells. Fuel cells are ecological and high efficiency sources of electric energy. However, the use of fuel cells on a large scale is limited, mainly by the high cost of catalysts. Platinum is most commonly used as the catalyst. But due to the high price of platinum there’s a need for finding other catalysts. Replacement of platinum will contribute to the fast development of green energy sources. This paper presents a study of possibility of using Cu-B alloy as catalyst for oxygen electrode in fuel cells. Researches were done in glass vessel, on a copper electr…

cathodeMaterials scienceenvironmental engineeringAlloyMetallurgyProton exchange membrane fuel cellengineering.materialDirect-ethanol fuel cellCathode catalystfuel cellCu-B alloyoxygen electrodeengineeringFuel cellsrenewable energy sourcesQUAESTI-Virtual Multidisciplinary Conference
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USE OF Ni-Co ALLOY AS CATHODE CATALYST IN SINGLE CHAMBER MICROBIAL FUEL CELL

2017

Technology of microbial fuel cells allowing for the direct production of electricity from biodegradable materials can provide only energy production, but also wastewater treatment. This technology is seen as supporting of the traditional wastewater treatment. One of the problems with microbial fuel cells is a low current density of those energy sources. Nonetheless, it is possible to increase the current density by using the catalyst for electrodes (anode and cathode). The possibility of wastewater treatment using the Ni-Co alloy as catalyst for single chamber microbial fuel cells is presented in this paper. The studies have included measurements of H2O2 reduction on Ni-Co catalyst, power o…

lcsh:GE1-350environmental engineeringMicrobial fuel cellMaterials science020209 energyMetallurgyAlloy02 engineering and technologyCODengineering.materialCathode catalystmicrobial fuel cellNi-Co alloy0202 electrical engineering electronic engineering information engineeringengineeringCatalystrenewable energy sourceslcsh:Environmental sciencesSingle chamberInżynieria Ekologiczna
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